幾種新型含氧燃料的燃燒反應動力學研究-英文 孫雯禹 9787302631125 【台灣高等教育出版社】

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書名:幾種新型含氧燃料的燃燒反應動力學研究-英文
ISBN:9787302631125
出版社:清華大學
著編譯者:孫雯禹
頁數:215
所在地:中國大陸 *此為代購商品
書號:1597237
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內容簡介

本書針對幾類新型含氧燃料,選取其中具有代表性的典型化合物,包括碳酸二甲酯、碳酸二乙酯、環戊酮、3-戊酮、乙二醇二甲醚和二甲氧基甲烷,開展燃燒反應動力學研究。實驗方面,選取合適的診斷方法測量了目標燃料在不同工況下詳細的組分信息;動力學模型方面,通過高精度理論計算獲取了關鍵基元反應的速率常數,在此基礎上發展了經過驗證的具有良好預測性能的燃燒反應動力學模型。 本書可供燃燒反應動力學等領城的高等院校師生和科研院所研究人員及相關技術人員閱讀參考。

目錄

Chapter 1 Introduction
1 1 Background
1 1 1 The significance of biofuels to energy, climate and environment
1 1 2 Novel oxygenated fuels and emission tests in engines
1 1 3 Kinetic studies on the combustion of oxygenated fuels
1 2 The object of this book and relevant research in literature
1 2 1 Research objects
1 2 2 Status of related research
1 3 The research content and chapter arrangement of this book
Chapter 2 Experimental, kinetic modeling and theoretical methods
2 1 Experimental methods
2 1 1 The low-pressure laminar premixed flame experimental set-ups
2 1 2 The flow-tube reactor pyrolysis experimental set-up
2 1 3 The jet-stirred reactor (JSR) oxidation experimental set-up
2 2 Kinetic modeling methods
2 2 1 Construction of kinetic reaction mechanism
2 2 2 Thermodynamics and transportation parameter acquisition
2 2 3 Kinetic simulation method
2 3 Theoretical calculation method
2 3 1 Ionization energies calculation
2 3 2 Rate coefficients calculation
Chapter 3 High-temperature combustion kinetics of carbonate ester and ketone fuels
3 1 Introduction
3 2 The high-temperature oxidation and pyrolysis kinetics of dimethyl carbonate
3 2 1 Kinetic model development
3 2 2 DMC pyrolysis in a flow tube
3 2 3 Low-pressure laminar premixed flames of DMC
3 2 4 Comprehensive validations of the kinetic model
3 3 The high-temperature oxidation and pyrolysis kinetics of diethyl carbonate
3 3 1 Kinetic model development
3 3 2 DEC pyrolysis in a flow tube
3 3 3 Laminar premixed flames of DEC
3 4 Comparison of combustion characteristics of DMC and DEC
3 5 Experimental and kinetic modeling study of low-pressure premixed flames fueled by two C5 ketones
3 5 1 Kinetic model development
3 5 2 Fuel consumptions and primary intermediates formation
3 5 3 Formation of pollutant precursors
3 6 Summary
Chapter 4 The low temperature oxidation kinetics of polyether fuels
4 1 Introduction
4 2 Low-temperature oxidation kinetics of 1,2-dimethoxyethane (1,2-DME)
4 2 1 Experimental condition
4 2 2 Kinetic model development
4 2 3 JSR low-temperature oxidation of ethylene glycol dimethyl ether
4 2 4 Model validation under premixed flame conditions
4 3 Low-temperature oxidation kinetics of dimethoxymethane (DMM)
4 3 1 Experimental conditions
4 3 2 Kinetic model development
4 3 3 Low-temperature oxidation reactivity and species formation
4 4 Summary
Chapter 5 The blending effects of oxygenated additives under premixed flame conditions
5 1 Introduction
5 2 Experimental conditions
5 3 Premixed flames fueled by ethane and DMM (or DMC) blends
5 3 1 Model construction and validation
5 3 2 Results and discussion
5 4 Premixed flames fueled by benzene and ethanol (or DME) blends
5 4 1 Kinetic model development
5 4 2 Results and discussion
5 5 Summary
Chapter 6 Conclusions and perspectives
6 1 Major conclusions
6 2 Main innovations
6 3 Perspectives
References
Appendix A Nomenclature of species involved in low-temperature oxidation of polyether fuels
Appendix B Chemical structures of the premixed flames fueled by binary fuels used for model validation
Acknowledgements

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